Integrated infrared optical antenna and polaronic organic transducer sensor

ABSTRACT

An antenna array is provided including a substrate, a metal ground plane proximate the substrate, and a dielectric layer proximate the metal ground plane. A first plurality of antenna elements including polaronic organic transducer elements is proximate the dielectric layer and connected in series. A second plurality of antenna elements including polaronic organic transducer elements is proximate the dielectric layer and also connected in series. The first and second plurality of antenna elements are electrically isolated. The antenna elements of the first plurality of antenna elements are configured to detect a first wavelength, while the antenna elements of the second plurality of antenna elements are configured to detect a second wavelength, different from the first wavelength.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a divisional of U.S. application Ser. No.15/424,961, entitled “Integrated Infrared Optical Antenna and PolaronicOrganic Transducer Sensor,” filed on Feb. 6, 2017, which is acontinuation of U.S. application Ser. No. 15/422,497, entitled“Integrated Infrared Optical Antenna and Polaronic Organic TransducerSensor,” filed on Feb. 2, 2017, the entirety of which is incorporated byreference herein.

RIGHTS OF THE GOVERNMENT

The invention described herein may be manufactured and used by or forthe Government of the United States for all governmental purposeswithout the payment of any royalty.

BACKGROUND OF THE INVENTION Field of the Invention

The present invention generally relates to multispectral imaging,detection, and tracking of objects and, more particularly, to an antennaand transducer sensor for the multispectral imaging, detection, andtracking.

Description of the Related Art

Contemporary infrared detectors generally consist of photoconductors,photo-emissive detectors, and photodiodes. Photoconductors absorbphotons or light changing their conductance. Photo-emissive detectorsconsist of an anode and photocathode. A photon hits the cathode and anelectron is ejected, which is collected at the anode, producing acurrent in the detector. A photodiode is rectifying junction, which canproduce a voltage or current when a photon is absorbed. Focal planearrays (FPAs) are arrays of photodiodes that can sense a change inintensity of light across the array, producing an image. TypicalInfrared (IR) FPAs are made from semiconducting materials such asmercury-cadmium-telluride (MCT), indium gallium arsenide (InGaAs), andindium antimonide (InSb), among others, which determine the spectralresponse of the FPA. The FPA is hybridized to a readout integratedcircuit (ROIC), from which data is sequentially readout. The readoutsignal can be processed to form an image, to calculate a trajectory, orto determine a spectral signature of an object. The detectors do nothave an inherent capability for wavelength selective detection withoutexternal media such as spectral filters and phase and diffractiongratings. Moreover, the high cost of quality MCT, InGaAs and InSb FPAsbecomes prohibitive for very large area infrared detectors.Additionally, the capacitance of each detector pixel is directly relatedto its size and presents challenges for accurate, extremely fast(sub-nanosecond) object tracking. Thus, to achieve a goodsignal-to-noise performance and a very fast response, contemporarydetectors may also require cryogenic cooling to assist in preventingthermal generation of charge carriers.

Contemporary sensing systems require detection of multiple wavelengthbands in the visible and infrared regions, among others. Visible imagingis commonly accomplished using silicon charge capture devices (CCDs),while imaging in the infrared region is commonly accomplished using MCT,InSb, and InGaAs cameras. All of the infrared detectors require adetector array cooled thermoelectrically or cryogenically. Both optionshave limitations with regards to cost, time, and performance. The ROICadds considerable weight and cost to the detector; cryogenic andthermoelectric cooling limit platform mission time and increase powerconsumption, respectively. Based on well known, establishedtechnologies, these detectors are also susceptible to an array ofcountermeasure systems, do not have inherent wavelength-selectivedetection, and require complex signal processing algorithms for objecttracking.

Accordingly, there is a need in the art for a means of object trackingwith sub-nanosecond time resolution using a detector inherently capableof wavelength-selective detection and without expensive detectormaterials that require cryogenic cooling.

SUMMARY OF THE INVENTION

Embodiments of the integrated sensor address the need in the art byproviding an inexpensive, high speed, ambient temperature, andspectrally selective sensor. In some embodiments, an antenna element isutilized having a first antenna component, a graphene layer proximatethe first antenna component, a doped, conjugated organic polymerproximate the graphene layer, and a second antenna component proximatethe doped, conjugated organic polymer forming an organic polymercapacitor between the first and second antenna components. In someembodiments, configurations of the antenna elements may include dipole,bow tie, log-periodic, Yagi-Uda, and patch configurations, among others.In some of these embodiments, the first and second antenna componentsform connections for respective first and second poles of the antennaelement.

Additionally, embodiments of the invention also provide an antenna arrayincluding a substrate, a metal ground plane proximate the substrate, anda dielectric layer proximate the metal ground plane. A first pluralityof antenna elements is proximate the dielectric layer and connected inseries. A second plurality of antenna elements is also proximate thedielectric layer and connected in series. The first and second pluralityof antenna elements are electrically isolated. Antenna elements of thefirst plurality of antenna elements are configured to detect a firstwavelength. And, antenna elements of the second plurality of antennaelements are configured to detect a second wavelength, different fromthe first wavelength.

In some embodiments, the antenna array further includes a thirdplurality of antenna elements proximate the dielectric layer andconnected in series. The first, second, and third plurality of antennaelements are electrically isolated. And, in these embodiments, theantenna elements of the third plurality of antenna elements areconfigured to detect a third wavelength, different from the first andsecond wavelengths.

In some of these embodiments, a thickness of the metal ground plane maybe between 250 nm and 350 nm. Also, in some of these embodiments, athickness of the dielectric layer may be approximately one quarterwavelength of an operational wavelength region.

Finally, embodiments of the invention additionally provide a system,which includes an antenna array comprising a plurality of rows ofantenna elements connected in series, electronics to detect and amplifychanges in DC voltages produced by each row of the plurality of rows ofantenna elements, and multichannel analog to digital converters inelectrical communication with the electronics and configured to digitizedata from the electronics. Each row of antenna elements of the pluralityof rows of antenna element is configured to detect a unique wavelengthwith respect to the other rows of antenna elements of the plurality ofrows of antenna elements.

Additional objects, advantages, and novel features of the invention willbe set forth in part in the description which follows, and in part willbecome apparent to those skilled in the art upon examination of thefollowing or may be learned by practice of the invention. The objectsand advantages of the invention may be realized and attained by means ofthe instrumentalities and combinations particularly pointed out in theappended claims.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are incorporated in and constitute apart of this specification, illustrate embodiments of the invention and,together with a general description of the invention given above, andthe detailed description given below, serve to explain the invention.

FIG. 1 is a representation of an integrated optical antenna and apolaronic organic transducer sensor;

FIG. 2 is a cross section of the integrated optical antenna and apolaronic organic transducer sensor of FIG. 1;

FIG. 3 is representation of a three element, linear array consisting ofthe integrated optical antenna and a polaronic organic transducersensors of FIG. 1;

FIG. 4A illustrates a schematic diagram of one row of in antennaelements (AE) with an optically generated voltage, V_(row), acrosselements AE 11 through AE 1 m;

FIG. 4B illustrates a schematic diagram of an equivalent electricalcircuit of FIG. 4A where each antenna element acts as a DC voltagesource, V₁ to V_(m), which are connected in series and summed, producinga total voltage, V_(row);

FIG. 5 illustrates a schematic diagram of rows of in-elementantennas-transducers, producing a sum row voltage, V_(row), forming anarray of n rows; and

FIG. 6 illustrates a schematic diagram of a high level system includingan n×m antenna element array of FIG. 5 designed for threat detection andsignal processing.

It should be understood that the appended drawings are not necessarilyto scale, presenting a somewhat simplified representation of variousfeatures illustrative of the basic principles of the invention. Thespecific design features of the sequence of operations as disclosedherein, including, for example, specific dimensions, orientations,locations, and shapes of various illustrated components, will bedetermined in part by the particular intended application and useenvironment. Certain features of the illustrated embodiments have beenenlarged or distorted relative to others to facilitate visualization andclear understanding. In particular, thin features may be thickened, forexample, for clarity or illustration.

DETAILED DESCRIPTION OF THE INVENTION

Traditionally, antennas are resonant structures designed to be used inradio frequency (RF) detection, but they may also be designed to senseelectromagnetic radiation in the 400 nm-3000 nm wavelength range, whichis the visible-shortwave infrared (VIS-SWIR) region. Embodiments of theinvention including a VIS-SWIR integrated antenna and polaronic organicsensor described herein contain a doped, conjugated, organicpolymer-graphene thin film acting as a fast, room temperature signaltransducer and a dipole antenna. The antenna acts as a wavelengthselective, resonant spectral filter. In some embodiments, the integratedantenna and polaronic sensor may be fabricated in linear arrays of 20 to40 antenna-polaronic integrated sensors connected in series. Thisarrangement may produce a sum of the voltages across the integratedsensor array in an array that is the size of a typical FPA pixel.Furthermore, embodiments of the integrated sensor array may be designedto operate at selected VIS-SWIR wavelengths. Signals from each array maybe readout by pulse capture hardware and in some embodiments transferredto a sensor specific processing unit to be processed by algorithms thatcan identify and or track an object from the electromagnetic radiationemitted by that object. Although the sensors may be cooled in someembodiments, the sensors may also operate at ambient temperatures.

Antennas may be designed to operate in specific spectral regions. Forsome embodiments of the invention, the integrated antenna-polaronicorganic sensors may be designed for wavelengths in the 400 nm-3000 nmspectral range. Turning now to FIG. 1, an exemplary design of anintegrated sensor 10 includes a dipole antenna 12 connected to agraphene (or an electron donating organic molecule) and doped conjugatedorganic polymer capacitor 14. Each leg 16 a, 16 b of the dipole antenna12 is attached to each side of the organic capacitor 14. The capacitor14 has two metal like layers 18, a graphene layer 20, and a doped,conjugated, organic polymer layer 22, which can be seen in the crosssection of the integrated sensor 10 in FIG. 2. The graphene 20 anddoped, conjugated, organic polymer layer 22 are between the two metallayers 18, which act as connections for the dipole antenna 12. Lightwill excite the resonance of the antenna and this resonance excitespolaronic species in the graphene-doped, conjugated polymer, creating apotential difference across the capacitor 14. The integrated antenna andpolaronic organic sensor 10 may be situated on a dielectric material 24one quarter wavelength above a ground plane 26 (seen in FIG. 3).

The integrated antenna polaronic organic sensors 10 shown in FIGS. 1-3,are capable of inherently discriminatory detection of selectedwavelengths at room temperature. Embodiments employing the integratedsensor arrays may also have a native object tracking ability usingsimpler signal processing algorithms. As a result, the complexity ofwavelength selective detection and object tracking may be reduced whilethe operating temperature of the detector may be increased.

In the illustrated embodiment, the antennas 12 have lengths ofapproximately one-half of their resonant wavelength, which significantlyincreases the spatial resolution of detectors in the 400 nm-3000 nmregion, compared to contemporary FPA and CCD pixel sizes of 4-20 μm.Actual detector dimensions, made from arrays of antenna-transducerelements, depend on a desired resonance wavelength of the antennas 12, arequired spatial resolution of the detector, and a number of wavelengthbands to detect, among other factors.

Antenna designs commonly encountered in radiofrequency and millimeterwave communications include dipole, bowtie, log-periodic, Yagi-Uda,patch, among others. These types of antennas may be scaled down forresonance at selected wavelengths between 400 nm-3000 nm. In theillustrated embodiment in FIGS. 1-3, a dipole antenna design is shown,though other embodiments may utilize other antenna designs. To fabricatean antenna array shown in FIGS. 1-3, a substrate 24 material is chosen.The material of this substrate is not critical since no electromagneticradiation will be propagating through the material. In the illustratedembodiment silicon was used for the substrate. Since the ground planedefines the electrical boundary condition, any substrate may be usedthat meets the system requirements. A metal is deposited on thesubstrate 24 to a thickness of 300 nm±50 nm to act as a ground plane 26.The choice of metal for the embodiments will depend on the spectralrange of operation of the detector. For the illustrated embodiment goldwas used. An aluminum oxide (Al₂O₃) dielectric layer 28 is thendeposited over the ground plane 26 approximately one quarter wavelengththick at an operational wavelength region of 780 nm-1450 nm. Metal 18for the bottom dipole antennas and bottom transducer pads is thenpatterned on the quarter wavelength thick substrate 28. A doped,conjugated organic polymer 20 is deposited on the bottom transducer padmetal 18. Graphene 22 is then transferred or grown on top of the doped,conjugated organic polymer 20. In other embodiments, as an alternativeto graphene, any electron donating organic molecule, such astriphenylamine, may also be used. Deposition follows of metallic film 18to make the top dipole antennas and top transducer pads. Separateconductive air bridges 30 are patterned to connect half of each dipoleantenna to the top transducer pad, to connect adjacent integrated sensorelements in series, and to connect integrated sensor arrays tomultichannel pulse capture electronics. The conductive air bridges 30may consist of any electrically non-insulating material. The conductiveair bridges in the illustrated embodiment are metallic, though one couldalso use a semiconductor, etc.

For illustrative purposes, a 1×3 integrated sensor array is shown inFIG. 3, although actual systems will generally have larger numbers ofantennas. FIG. 3 is not drawn to scale and the structure is terraced forillustrative purposes to make it easier to see the layered structure.Here, the three element, linear array is depicted solely to illustratethe detector structure and connectivity between adjacent antennatransducer elements. The actual detector dimensions depend on thedesired resonance wavelength of the antennas, the required spatialresolution of the detector, and the number of wavelength bands todetect, among other factors. As a reference point, however, each antennaelement in this illustrated embodiment is approximately one-halfwavelength long.

Polymer polythiophene (PT) is used as a representative doped, conjugatedorganic polymer in the illustrated embodiment, though other conjugatedorganic polymers, such as polyfluorene, poly(phenylene-ethynylene),poly(p-phenylene), poly(p-phenylenevinylene), polyaniline,poly(thienylene vinylene), and polypyrrole may also be used. The PT isdoped with tetrafluoroborate anions (BF₄ ⁻) resulting in a positiveelectrical charge on the PT. Other dopants may also be used, such asperchlorate, chloride, bromide, iodide, sodium, tetra-n-butylamine, andphotodoping, depending on the system requirements. For the illustratedembodiment, in its undoped state, the highest occupied molecular orbital(HOMO) of PT is −5.29 eV and that of graphene is −4.5 eV. Generally, forBF₄ ⁻ doped PT, this is too high of an energy barrier for a positivecharge to migrate from PT to graphene efficiently. However, a thin filmof BF₄ ⁻ doped PT features an electron transition attributed bipolaronexcitation at 1698 nm. Until relaxation occurs, the energy of BF₄ ⁻doped PT is increased to −4.56 eV. This reduces the energy barrier forcharge migration, allowing a pair of electrons to transfer to BF₄ ⁻doped PT and a pair of positively charged polarons to transfer tographene. Thus BF₄ ⁻ doped PT acts as a charge donor and graphene actsas a charge acceptor. The resulting movement of charge results in apositive electric voltage in the organic transduction layer.

FIG. 4A is a schematic representation of each antenna element in a 1×msensor array. Antennas AE-11 through AE-1 m (the mth antenna element)each produce their own photovoltage. An equivalent circuit diagram shownin FIG. 4B depicts each of these antenna elements as a voltage source V₁to V_(m), where m is the last element of the row. These voltage sourcesare connected in series, producing a total voltage V_(row), which may beread out by pulse capture electronics (such as front end analogcircuitry 44 in FIG. 6). In an alternate illustrated embodiment show inFIG. 5, an array is comprised of n rows and m antenna elements, whereeach row may be tuned to a different wavelength, providing amulti-spectral response out of the n row configuration. Each row maysimilarly produce a total voltage V_(row) ₁ through V_(row) _(n) , whichmay also be read out by pulse capture electronics and then furtherprocessed as illustrated in more detail below.

FIG. 6 illustrates an embodiment of an overall architecture 40 of anantenna system. A detector 42 including n rows with m antenna-transducerelements as illustrated above, where each row is configured to detect adifferent wavelength, is captured by front end analog circuitry 44. Aphotovoltage from each row may read and captured by level sensitiveelectronics 46. Additionally, multichannel analog-to-digital converters(ADCs) 48 may be used to digitize the data for filtering and signalreconstruction. Voltage readouts from each individual row are capturedby front end analog circuitry 46. These level sensitive electronics 46detect changes in DC voltages produced by the rows of antenna elementsand amplify them for further processing. Multichannel ADCs 48 will thendigitize the data for digital signal processing algorithms. The antennaarray 42 front end is geared towards a rapidly evolving point target;therefore, no algorithmic template matching is required. This filteringaspect of the antenna array 42 by design also provides acounter-countermeasure (CCM) against an adversary platform. Any numberof multi-spectral algorithms may then be employed for signal processingand reconstruction as illustrated in the graph 50.

By combining, in one detector, arrays of antennas, each resonant atdifferent wavelengths, a sensor with inherent wavelength-selectivedetection is created. A multi-spectral analysis algorithm targeted forthis sensor may perform more efficiently as it does not have to processa large number of spectral bands found in traditional multi orhyper-spectral systems. These systems may have from tens to hundreds ofspectral bands producing responses of varying amplitude and shape to athreat or a set of threats. Processing more bands is more challenging asit requires more hardware and time to process the data. This approach ismore prone to errors due to the output response of various sources thatmay be present in the field of view (FOV) and may amplify or attenuatethe signal. The end result may result in false alarms or missed targetsdue to the above mentioned artifacts.

Algorithms working with the embodiments of the invention utilize areduced data set produced by the sensor in a small number of preselectedspectral bands of interest to discriminate a threat in the sensor's FOV.Only one data point per row is collected and a reduced data set may thenbe developed after discretization of the data. This assists in ensuringmaximum system response to a specific threat stimulus for a givenspectrum for detection and may also assist in being more isolated fromnoise and natural artifacts that may corrupt the spectral signature ofinterest. The multi-spectral algorithm may then correlate thecharacterization data set to the system response in determination of atarget or a threat. The reduced data set also generally requires lessprocessing, translating to less hardware requirements and shorterprocessing times. Since the antenna itself will behave as a filter forwavelengths of interest, the signal to noise ratio (SNR) will generallybe high, increasing the precision and sensitivity of the system. This,in turn, contributes towards efficiency and reduced computationalintensity of the algorithm.

While the present invention has been illustrated by a description of oneor more embodiments thereof and while these embodiments have beendescribed in considerable detail, they are not intended to restrict orin any way limit the scope of the appended claims to such detail.Additional advantages and modifications will readily appear to thoseskilled in the art. The invention in its broader aspects is thereforenot limited to the specific details, representative apparatus andmethod, and illustrative examples shown and described. Accordingly,departures may be made from such details without departing from thescope of the general inventive concept.

What is claimed is:
 1. A system comprising: an antenna array comprisinga plurality of rows of antenna elements connected in series; electronicsto detect and amplify changes in DC voltages produced by each row of theplurality of rows of antenna elements; and multichannel analog todigital converters in electrical communication with the electronics andconfigured to digitize data from the electronics, wherein each row ofantenna elements of the plurality of rows of antenna element isconfigured to detect a unique wavelength with respect to the other rowsof antenna elements of the plurality of rows of antenna elements, andwherein the antenna elements of the plurality of rows of antennaelements comprise: a first antenna component; a layer of electrondonating organic molecules proximate the first antenna component; adoped, conjugated organic polymer proximate a graphene layer; and asecond antenna component proximate the doped, conjugated organic polymerforming an organic polymer capacitor between the first and secondantenna components.
 2. The system of claim 1, wherein the antenna arrayfurther comprises: a substrate; a metal ground plane proximate thesubstrate; and a dielectric layer proximate the metal ground plane,wherein the plurality of rows of antenna elements is proximate thedielectric layer.
 3. The system claim 2, wherein a thickness of themetal ground plane is between 250 nm and 350 nm.
 4. The system of claim2, wherein a thickness of the dielectric layer is approximately onequarter wavelength of an operational wavelength region.
 5. The system ofclaim 1, wherein the layer of electron donating organic moleculescomprises triphenylamine.
 6. The system of claim 1, wherein aconfiguration of the antenna element is selected from a group consistingof: dipole, bow tie, log-periodic, Yagi-Uda, and patch configurations.